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Part 01 · Atomic structure and periodic trends · Card 5 of 10

Atomic orbital

An orbital is a region around the nucleus where an electron is most likely to be found. An s orbital is a sphere. A p orbital is shaped like a dumbbell. Each orbital holds at most two electrons.

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Analogy

Like a cloud of mist rather than a racetrack: dense where the electron is likely, thin where it is not.

Example

Orbitals per subshell

s: 1 orbital (2 electrons)p: 3 orbitals (6 electrons)d: 5 orbitals (10 electrons)f: 7 orbitals (14 electrons)

In practice

The shape of orbitals decides the shape of molecules, because bonds form where orbitals overlap.

Practice

Flashcards

  • How many orbitals are in a p subshell, and how many electrons fit?Three orbitals, holding up to six electrons.

Questions people ask

Is an orbital the same as an orbit?

No. An orbit, from the old Bohr model, was a fixed circular path. An orbital is a probability map showing where an electron is likely to be found. The electron has no exact path, so we can only describe how likely each place is.

What is a node in an orbital?

A node is a place where the chance of finding the electron is zero. A 2s orbital has one spherical node inside it. A 2p orbital has a flat node through the nucleus, which is why the two lobes of a dumbbell are separated.